XML File
<?xml version="1.0" encoding="utf-8" ?>
<Students>
  <Student>
    <Name>Vijay kumar</Name>
    <Class>8th</Class>
    <Roll>50</Roll>
    <Section>E</Section>   
  </Student>
  <Student>
    <Name>Narottam Dev Sharma</Name>
    <Class>10th</Class>
    <Roll>51</Roll>
    <Section>D</Section>
  </Student>
  <Student>
    <Name>Shyam Sudar</Name>
    <Class>12th</Class>
    <Roll>52</Roll>
    <Section>F</Section>
  </Student>
  <Student>
    <Name>Umesh kumar</Name>
    <Class>8th</Class>
    <Roll>49</Roll>
    <Section>E</Section>
  </Student>
</Students>

.aspx FILE:

Code File:

using System;
using System.Collections;
using System.Configuration;
using System.Data;
using System.Linq;
using System.Web;
using System.Web.Security;
using System.Web.UI;
using System.Web.UI.HtmlControls;
using System.Web.UI.WebControls;
using System.Web.UI.WebControls.WebParts;
using System.Xml.Linq;

public partial class DisplayXML : System.Web.UI.Page
{
    protected void Page_Load(object sender, EventArgs e)
    {
        DataSet ds = new DataSet();
        ds.ReadXml(MapPath("XMLFile.Xml"));
        GridView1.DataSource = ds;
        GridView1.DataBind();
    }
}